Page 20 - PEN eBook December 2022
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SEMICONDUCTORS                                                                                                                                                                                      Semiconductors



                                                                                                                                   To maximize the potential of a novel semiconductor technology, the industry must make a concerted
                                                                                                                                   effort to solve technical obstacles that hinder performance. Significant technological advancement
                                                                                                                                   has taken place in the field of ultra-wide–bandgap semiconductors since 2016, when Flosfia, a

                                                                                                                                   spinoff from Kyoto University specialized in R&D and commercialization of gallium oxide thin films,
                                                                                                                                   concluded that gallium oxide warranted development.


                                                                                                                                   The semiconductor industry is increasingly moving  toward implementing devices built  from
                                                                                                                                   wide-bandgap materials such as silicon carbide and gallium nitride, but the cost of those materials
                                                                                                                                   remains relatively high. In response, researchers more recently have pursued development of
                                                                                                                                   beta-gallium oxide (β-Ga O ), a stable phase of  the compound.  β-Ga O  development is a
                                                                                                                                                             2  3                                            2  3
                                                                                                                                   result of an increased  focus on materials research  to improve  the overall performance of
                                                                                                                                   power-electronic devices over the junction-based approaches of the past. β-Ga O  stands out for its
                                                                                                                                                                                                                2  3
                                                                                                                                   intrinsic properties, including an ultra-high bandgap (an energy gap of 5 eV), good conductivity and
                                                                                                                                   field-holding capacity, and high critical field strength, with the highest ever demonstrated being
                                                                                                                                   5.5 MV/m.


                                                                                                                                   Processing the material in different ways can result in a variety of properties, demonstrating its
                                                                                                                                   flexibility. For example, doping the material from a melt results in a resistivity of 10 mΩ-cm; silicon
                                                                                                                                   implantation can decrease it to 1 mΩ-cm. Halide vapor epitaxy on the material can be controlled to

                                                                                                                                   have a doping concentration in the range of 10  to 10  cm .
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                                                                                                                                                                                            –3
                                                                                                                                                                                 15
                                                                                                                                   Fabricating      standard
                                                                                                                                   features onto  β-Ga O
            Gallium Oxide: A                                                                                                       is also relatively easy.
                                                                                                                                                            3
                                                                                                                                                          2
                                                                                                                                   For  example,  ohmic  and
            Next-Gen                                                                                                               Schottky contacts can
                                                                                                                                   be made using standard

            Semiconductor for                                                                                                      metals    like   titanium,
                                                                                                                                   aluminum,  and  nickel  at
                                                                                                                                   relatively low annealing
            Power Devices                                                                                                          temperatures.



                                                                                                                                   Wafering and lapping of
            By Maurizio Di Paolo Emilio                                                                                            the material can be done

                                                                                                                                   using standard production

            In the past decade, gallium oxide has seen fast technical development, propelling it to the forefront                  tools.  Different  dielectric   Figure 1: A top-level view of the technology progress for various sectors toward
            of ultra-wide–bandgap semiconductor technologies. The major targeted application space is power                        materials,  such  as  Al O    commercialization of β-Ga O  applications as of October 2021 (Source: Link)
                                                                                                                                                                                      2
                                                                                                                                                                                        3
                                                                                                                                                          2  3
            electronics,  in which  gallium  oxide’s  intrinsic  material  properties  —  high  critical field  strength,          deposited     using   the
            widely tunable conductivity, low mobility, and melt-based bulk growth — promise to deliver the                         atomic layer deposition method, can be used as gate dielectrics (Figure 1).
            required high performance at low cost.




  36        DECEMBER 2022 | www.powerelectronicsnews.com                                                                                                                             DECEMBER 2022 | www.powerelectronicsnews.com           37
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