Page 46 - PEN eBook October 2025
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SEMICONDUCTORS                                                                                                                                                                                                  SEMICONDUCTORS

                                                               This process uses silicon sludge, which could be
                                                              waste generated, for example, during the slicing
                                                              process of the manufacture of silicon substrates.
                                                              Carbon dioxide (CO ) is the other input used in
                                                                                2
                                                              this process. CO  is a greenhouse gas, and its
                                                                             2
                                                              capture and reuse in the production of a valuable
                                                              raw material essential for SiC wafer manufacturing
                                                              showcases a technique that can lower the overall
                                                              environmental impact in SiC device manufacturing. In
                                                              Tohoku University’s process, microwaves were used
                                                              to heat the silicon sludge and create the reaction
                                                              with CO  through the process of mineralization.
                                                                      2
                                                              Figure 2 showcases this innovative waste-reusage
                                                              technology for the application of SiC power device
                                                              manufacturing.
          Figure 1: Depiction of the Acheson process and the
          alternative Tohoku University process for manufacturing   In July 2025, Resonac and Tohoku University
          SiC powder                                          announced that basic research into this process has
                                                              been completed. This includes the characterization
          front-end manufacturing chemicals such as gases,    of the SiC crystals obtained through the use                       Figure 2: Resonac and Tohoku University collaboration for SiC power device manufacturing (Source: Resonac Corporation)
          solvents, and slurries, back-end materials such as   of SiC powder using this new mineralization
          encapsulants and molds, epitaxial wafers, LED chips,   method. Comprehensive studies for the practical
          and more. SiC epitaxial wafers are part of its product   implementation of this are now being pursued. It              COLD-SPLITTING SiC SUBSTRATES                       been used to create a variety of SOI wafers used in
          portfolio. Tohoku University conducted research aimed   is estimated that 100 tons of SiC powder produced               SiC wafers are typically sliced from ingots using a   applications such as bipolar-CMOS-DMOS, RF, and fully
          at creating an environmentally friendly manufacturing   would lead to the equivalent reduction of 110 tons             diamond saw and abrasive slurries. This results in   depleted SOI used in advanced, high-speed,
          process for SiC powder, which is a key starting point   of CO . It also allows the recycling of silicon sludge         significant material loss and waste. In 2018, Infineon   mixed-signal applications.
                                                                   2
          for SiC wafer manufacturing. Figure 1 depicts the   waste produced in the large-scale manufacturing of                 Technologies, a large manufacturer of SiC power devices
          comparison between the traditional Acheson process   CMOS devices.                                                     and modules, acquired Siltectra. Siltectra developed   Soitec’s SmartSiC technology extends the SmartCut
          and the method developed by Tohoku University.                                                                         the innovative Cold Split technology. This method uses   process to SiC wafer fabrication. Some key differences
                                                                                                                                 a laser to create a pre-damaged layer in the SiC crystal.   are that the handle wafer is now highly doped
                                                                                                                                 A special polymer is applied to the surface of the SiC   poly-SiC. The bonding process is also conductive,
                                                                                                                                 boule after the laser line is created. Liquid nitrogen   allowing for a vertical SiC device to be created, as with
                                                                                                                                 cooling causes mechanical stress from the different   normal single-crystal SiC substrates. Standard SiC
                                                                                                                                 contraction rates of the polymer and the SiC, resulting   epi growth can be done over the top surface of the
                                                                                                                                 in SiC separation along the laser-damaged areas. This   thin slice of the silicon-facing SiC donor wafer that is
                                                                                                                                 application of the laser/polymer/cooling can be repeated   used over the handle wafer. Soitec has affirmed that
                                                                                                                                 to create the wafers with the thickness needed (the   using SmartSiC can result in an up-to-80% reduction
                                                                                                                                 standard substrate target is 350 µm). This process   in equivalent CO  emissions in the SiC substrate
                                                                                                                                                                                                    2
                                                                                                                                 reduces waste and improves utilization of the valuable   manufacturing process. One key reason is that the
                                                                                                                                 SiC boule. Infineon has said that up to twice the number   poly-SiC wafers are much easier to produce through
                                                                                                                                 of SiC wafers can be produced by this method.       chemical vapor deposition, compared with the
                                                                                                                                                                                     high-temperature PVT process for monocrystalline SiC
                                                                                                                                 ENGINEERED SUBSTRATES                               fabrication.
                                                                                                                                  Soitec, a French company, developed its
                                                                                                                                 silicon-on-oxide (SOI) wafer technology in the 1990s.   Another key benefit is that that the donor wafer,
                                                                                                                                 This innovative technique is based on the SmartCut   which is expensive, can be used at least 10 times.
                                                                                                                                 process of film separation through implantation of   The lower substrate resistance (<5 mΩ-cm) of the
                                                                                                                                 hydrogen ions at a given depth onto an oxidized donor   poly-SiC can reduce net device resistance and
                                                                                                                                 wafer. After this high-dose implant, the wafer is flipped   hence conduction losses while at the same time
                                                                                                                                 and oxide-bonded onto a so-called handle wafer.     remove the requirement of the standard laser
                                                                                                                                 Thermal treatments split the donor wafer at the depth   backside anneal used in standard processing. The
                                                                                                                                 of the implant, with the part bonded onto the handle   process has been successfully demonstrated on
                                                                                                                                 wafer fused on it. The remaining donor wafer, which is   200-mm wafer diameters. Several wafer and device
                                                                                                                                 prime-grade silicon, can be now used for another SOI   manufacturers are partnering with Soitec on the
                                                                                                                                 wafer preparation. The depth of the hydrogen implant   SmartSiC technology, including Resonac, X-Fab, and
                                                                                                                                 can be precisely and uniformly controlled and has   STMicroelectronics.

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